Thermodynamic Calculation among Cerium, Oxygen, and Sulfur in Liquid Iron
نویسندگان
چکیده
Thermodynamic calculation has been applied to predict the inclusion formation in molten SS400 steel. When the Cerium addition in liquid iron is 70 ppm and the initial Oxygen and Sulphur are both 110 ppm, the formation of oxides containing Cerium would experience the transformation from Ce2O3 to CeO2 and also the formation of sulfides containing Cerium would experience the transformation from CeS to Ce2S3 and then to Ce3S4. Below 2000 K the most thermodynamic stable matter is CeO2 and the less thermodynamic stable inclusion is CeS. Only when the amount of [O] is extremely low and the amount of [S] and [Ce] is relatively high, Ce2S3 has the possibility to form.
منابع مشابه
Liquid-Vapor Density of Sulfur Hexaf luoride in the Critical Point
The thermodynamic properties of fluids can be predicted using the global equations of state. Among these thermodynamic properties of fluids, we choose the densities of the liquid and vapor phases. This paper considers the application of the crossover model to the vapor-liquid rectilinear diameter of sulfurhexafluoride. We also present a comparison of the crossover model equation with ...
متن کاملتوصیف ترمودینامیکی سیستم Ti-O براساس انتخاب مدل مایع یونی برای فاز مایع
In this study, the phase diagram and thermodynamic properties of Ti-O system up to 30 mole percent of oxygen was calculated with Calphad method. In this range of oxygen, Ti-O system includes αTi, βTi and liquid phases. αTi and βTi were modeled by “sublattice” model and the model of liquid phase was modeled by “ionic liquid”. Gibbs energy parameters ...
متن کامل1 Effect of the Chemical Composition of Mesoporous 2 Cerium - Zirconium Oxides on the Modification with 3 Sulfur and Gold Species and Their Application in 4 Glycerol Oxidation 5
Ceria, zirconia and mixed cerium-zirconium mesoporous oxides were synthesized and 12 used as supports for sulfur and gold species. The materials were characterised using selected 13 advanced techniques (ICP-OES, elemental analysis, XPS, XRD, N2 adsorption and desorption 14 isotherms, UV-vis, ATR-FTIR, TPR-H2, TG-DTA) which allowed monitoring of the oxidation state 15 of metals (cerium and gold)...
متن کاملMechanisms of enhanced sulfur tolerance on samarium (Sm)-doped cerium oxide (CeO2) from first principles.
The role of samarium (Sm) 4f states and Sm-perturbed O 2p states in determining the sulfur tolerance of Sm-doped CeO2 was elucidated by using the density functional theory (DFT) + U calculation. We find that the sulfur tolerance of Sm-doped CeO2 is closely related to the modification of O 2p states by the strong interaction between Sm 4f and O 2p states. In particular, the availability of unocc...
متن کاملThe Effect of Flux type and Oxygen Blowing on Simultaneous Removal of Phosphorus and Sulfur from Molten Iron
This research was conducted to study the effect of lime based Flux with the composition of CaO-20%CaF2-8%FeO on simultaneous removal of phosphorus and Sulfur from hot metal. The effects of Na2O and oxygen blowing were also studied. The experiments were performed using an induction furnace and hot metal produced in Isfahan Steel Company in the temperature range 1350-1450 ºC...
متن کامل